Skip to main content

Thank you for visiting nature.com. You are using a browser version with limited support for CSS. To obtain the best experience, we recommend you use a more up to date browser (or turn off compatibility mode in Internet Explorer). In the meantime, to ensure continued support, we are displaying the site without styles and JavaScript.

  • News & Views
  • Published:

Mechanochemistry

Demonstrated leverage

Comparing how cyclopropanated polymers with different backbones behave when stretched with an atomic force microscope reveals that it is not only the strained rings that influence the mechanochemical response, but that the structure of the polymer backbone itself is far from innocent in this regard.

This is a preview of subscription content, access via your institution

Relevant articles

Open Access articles citing this article.

Access options

Buy this article

Prices may be subject to local taxes which are calculated during checkout

Figure 1: Forces to be reckoned with.

References

  1. Huang, Z. & Boulatov, R. Chem. Soc. Rev. 40, 2359–2384 (2011).

    Article  CAS  Google Scholar 

  2. Black, A. L., Lenhardt, J. M. & Craig, S. L. J. Mater. Chem. 21, 1655–1663 (2011).

    Article  CAS  Google Scholar 

  3. Staudinger, H. & Heuer, W. Ber. Dtsch. Chem. Ges. 67, 1159–1164 (1934).

    Article  Google Scholar 

  4. Kauzmann, W. & Eyring, H. J. Am. Chem. Soc. 62, 3113–3125 (1940).

    Article  CAS  Google Scholar 

  5. Davis, D. A. et al. Nature 459, 68–72 (2009).

    Article  CAS  Google Scholar 

  6. Chen, Y. et al. Nature Chem. 4, 559–562 (2012).

    Article  CAS  Google Scholar 

  7. Black, A. L., Orlicki, J. A. & Craig, S. L. J. Mater Chem. 21, 8460–8465 (2011).

    Article  CAS  Google Scholar 

  8. Klukovich, H. M. et al. Nature Chem. 5, 110–114 10.1038/nchem.1540 (2013).

    Article  CAS  Google Scholar 

  9. Akbulatov, S., Tian, Y. & Boulatov, R. J. Am. Chem. Soc. 134, 7620–7623 (2012).

    Article  CAS  Google Scholar 

  10. Tian, Y. & Boulatov, R. ChemPhysChem 13, 2277–2281 (2012).

    Article  CAS  Google Scholar 

  11. Hermes, M. & Boulatov, R. J. Am. Chem. Soc. 133, 20044–20047 (2011).

    Article  CAS  Google Scholar 

  12. Craig, S. L. Nature 487, 176–177 (2012).

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Roman Boulatov.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Boulatov, R. Demonstrated leverage. Nature Chem 5, 84–86 (2013). https://doi.org/10.1038/nchem.1541

Download citation

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1038/nchem.1541

This article is cited by

Search

Quick links

Nature Briefing

Sign up for the Nature Briefing newsletter — what matters in science, free to your inbox daily.

Get the most important science stories of the day, free in your inbox. Sign up for Nature Briefing